COSTA NOVA CERAMIC METAL MARKING CLEANER
Safety Data Sheet
In compliance with Regulation (EC) No. 1907/2006 (REACH) as
amended by Regulation (EU) 2020/878
Reference Number: CN_001_a
Date of Issue: 13/12/2024 | Version: 1.0
SECTION 1: Product and company identication
1.1 Product Identication
Product Form: Mixture
Commercial Name: COSTA NOVA METAL MARKING CLEANER
Product Code: 560673997963 / O30601
1.2 Recommended use and restrictions on use
1.2.1 Recommended use
Intended for general public use
Use of the substance or mixture: Stainless steel cleaning product, metal cleaning product
Use of the substance or mixture: Cleaning product
1.2.2 Uses advised against
No additional information available
1.3 Supplier identication of the safety data sheet
GRESTEL - PRODUCTOS CERÂMICOS, SA
Zona Industrial de Vagos, Lote 78
3840-385 Vagos
Portugal
T: +351 – 234 798 133
costanova@costanova.pt
1.4. Emergency telephone number
Emergency number: +351 – 234 798 133 (09:00 – 16:30 UTC+0)
SECTION 2: Hazards Identication
2.1 Classication of the substance or mixture
Classication according to Regulation (EC) No. 1272/2008 [CLP]: Not classied
Adverse eects resulting from physicochemical properties, as well as eects on human health and the
environment
To the best of our knowledge, no specic risks are present if good hygiene and safety practices at work are
followed.
2.2 Label Elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]:
Precautionary Statements (CLP):
P102: Keep out of reach of children.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
EUH Statements:
EUH208: Contains reaction mass (3:1) of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-
2H-isothiazol-3-one (55965-84-9). May cause an allergic reaction.
2.3 Other Hazards
Other hazards that do not result in classication:
May cause eye irritation in sensitized individuals. Prolonged or repeated skin contact may cause
dermatitis and dryness.
This substance/mixture does not meet the PBT criteria of Annex XIII of the REACH Regulation.
This substance/mixture does not meet the vPvB criteria of Annex XIII of the REACH Regulation.
Does not contain substances classied as PBT/vPvB ≥ 0.1% based on the evaluation in compliance with Annex
XIII of REACH.
The mixture does not contain substances listed under Article 59(1) of REACH for endocrine-disrupting
properties or substances identied as endocrine disruptors at a concentration equal to or greater than 0.1%
according to the criteria established by Commission Delegated Regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605.
SECTION 3: Information on Composition
3.1 Substances
Not applicable
3.2 Mixtures
Designation
Product Identier
%
Classication
according to Regulation
(EC) No. 1272/2008
[CLP]
Reaction mass (3:1) of 5-
chloro-2-methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one
- CAS No.: 55965-84-9
- EC No.: 911-418-6
- Index No.: 613-167-00-5
0.00015 – < 0.0015
Acute Tox. 2 (Inhalation),
H330
Acute Tox. 2 (Dermal),
H310
Acute Tox. 3 (Oral), H301
Skin Corr. 1C, H314
Eye Dam. 1, H318
Skin Sens. 1A, H317
Aquatic Acute 1, H400
(M=100)
Aquatic Chronic 1, H410
(M=100)
Specic Concentration Limits
Designation
Product Identier
%
Classication
according to Regulation
(EC) No. 1272/2008
[CLP]
Reaction mass (3:1) of 5-
chloro-2-methyl-2H-
isothiazol-3-one and 2-
methyl-2H-isothiazol-3-
one
- CAS No.: 55965-84-9
- EC No.: 911-418-6
- Index No.: 613-167-00-
5
0.00015 – < 0.0015
(0.0015 ≤ C < 100) Skin
Sens. 1A, H317
(0.06 ≤ C < 0.6) Skin Irrit.
2, H315
(0.06 ≤ C < 0.6) Eye Irrit.
2, H319
(0.6 ≤ C ≤ 100) Skin Corr.
1C, H314
(0.6 ≤ C ≤ 100) Eye Dam.
1, H318
Full text of H and EUH statements: see Section 16
SECTION 4: First Aid Measures
4.1 Description of First Aid Measures
First aid in case of inhalation: Move the person to an outdoor area and ensure they are in a position that
does not hinder breathing.
First aid in case of skin contact: Wash skin with plenty of water. If irritation or rash occurs, consult a
doctor.
First aid in case of eye contact: As a precaution, rinse your eyes with water. Consult a doctor if pain or
redness persists.
First aid in case of ingestion: In case of discomfort, contact a poison information center or a doctor.
Rinse mouth with water.
4.2 Most Important Symptoms and Eects, Both Acute and Delayed
Symptoms/eects in case of ingestion: Ingestion may cause nausea, vomiting, and diarrhea.
4.3 Indication of Immediate Medical Attention and Special Treatment Needed
Symptomatic treatment.
SECTION 5: Fireghting Measures
5.1 Extinguishing Media
Suitable extinguishing media: Water spray, dry powder, foam, carbon dioxide.
Unsuitable extinguishing media: None, as far as we are aware.
5.2 Special Hazards Arising from the Substance or Mixture
Hazardous decomposition products in case of re: Carbon oxides (CO, CO₂).
5.3 Advice for Fireghters
Protection during reghting: Do not attempt to ght the re without appropriate protective equipment.
Use self-contained breathing apparatus. Full body protection is required.
Additional information: Fire residues and contaminated reghting water must be disposed of in
compliance with local regulations. Prevent reghting runo from entering sewers or waterways.
SECTION 6: Accidental Release Measures
6.1 Personal Precautions, Protective Equipment, and Emergency Procedures
General measures: In case of accidental spillage, the oor may become slippery. Clean up any spills as
soon as possible using an absorbent material to collect the spilled product.
6.1.1 For non-emergency personnel
Emergency procedures: Ventilate the spill area.
6.1.2 For emergency responders
Protective equipment: Do not engage in spill response without appropriate protective equipment. For
more information, refer to Section 8: "Exposure Controls/Personal Protection."
6.2 Environmental Precautions
Prevent release into the environment. Avoid entry into sewers and drinking water supplies. Notify
authorities if the product enters the sewer system or public waterways.
6.3 Methods and Materials for Containment and Cleanup
For containment: Stop the leak if it can be done safely.
Cleanup methods: Absorb spilled liquid with absorbent material.
Additional information: Dispose of solid materials or residues at an authorized facility. Flush residues
with large amounts of water.
6.4 Reference to Other Sections
For additional information, refer to Section 13.
SECTION 7: Handling and Storage
7.1 Precautions for Safe Handling
Precautions for safe handling: Ensure proper ventilation of the workplace. Avoid contact with skin and
eyes.
Hygiene measures: Do not eat, drink, or smoke while using this product. Wash hands after handling.
Remove contaminated clothing immediately and wash it before reuse.
7.2 Conditions for Safe Storage, Including Any Incompatibilities
Technical measures: Ensure proper ventilation of the storage area.
Storage conditions: Store in a well-ventilated place. Keep the container tightly closed.
Incompatible materials: Oxidizing agents.
Heat and ignition sources: The product does not pose a particular risk of re or explosion.
Mixed storage information: Keep away from oxidizing agents.
7.3 Specic End Uses
No additional information available.
SECTION 8: Exposure Controls/Personal Protection
8.1 Control Parameters
8.1.1 National occupational and biological exposure limit values
No additional information available.
8.1.2 Recommended monitoring processes
No additional information available.
8.1.3 Formation of atmospheric contaminants
No additional information available.
8.1.4 DNEL and PNEC
No additional information available.
8.1.5 Exposure control systems based on exposure ranges
No additional information available.
8.2 Exposure Controls
8.2.1 Appropriate Technical Controls
Technical controls: Ensure proper ventilation of the workplace.
8.2.2 Personal Protective Equipment
8.2.2.1 Eye and Face Protection
o Eye protection: Use safety glasses with splash protection.
8.2.2.2 Skin Protection
o Body and skin protection: Wear long-sleeved protective clothing.
o Hand protection: In case of repeated or prolonged contact, wear gloves. Follow the instructions
regarding permeability and penetration time provided by the glove manufacturer. The choice of
appropriate gloves depends on the material and other quality characteristics, which may vary by
manufacturer.
8.2.2.3 Respiratory Protection
o Respiratory protection: Not required under normal use conditions.
8.2.2.4 Thermal Hazards
o No additional information available.
8.2.3 Environmental Exposure Controls
Environmental protection: Avoid release into the environment.
SECTION 9: Physical and Chemical Properties
9.1 Information on Basic Physical and Chemical Properties
Property
Value
Physical state
Liquid
Color
White
Appearance
Emulsion
Odor
Pleasant
Odor threshold
Not available
Melting point
Not applicable
Freezing point
Not available
Boiling point
≈ 100 °C
Flammability
Not applicable
Explosion limits
Not available
Lower explosive limit
Not available
Upper explosive limit
Not available
Flash point
Not available
Auto-ignition temperature
Not available
Decomposition temperature
Not available
pH
3.5 – 4
Kinematic viscosity
Not available
Solubility
Not available
Octanol/water partition coeicient (Log Koa)
Not available
Vapor pressure
Not available
Vapor pressure at 50°C
Not available
Density
1.07 – 1.17 g/ml
Relative density
Not available
Relative vapor density at 20°C
Not available
Particle characteristics
Not applicable
9.2 Other Information
9.2.1 Information regarding physical hazard classes
No additional information available.
9.2.2 Other safety characteristics
No additional information available.
SECTION 10: Stability and Reactivity
10.1 Reactivity
The product is not reactive under normal conditions of use, storage, and transport.
10.2 Chemical Stability
Stable under normal conditions.
10.3 Possibility of Hazardous Reactions
No hazardous reactions are known under normal conditions of use.
10.4 Conditions to Avoid
None under the recommended storage and handling conditions (see Section 7).
10.5 Incompatible Materials
Oxidizing agents.
10.6 Hazardous Decomposition Products
Under normal storage and use conditions, hazardous decomposition products are not expected to
form.
SECTION 11: Toxicological Information
11.1 Information on Toxicological Eects
Property
Classication/Value
Acute toxicity (oral)
Not classied
Acute toxicity (dermal)
Not classied
Acute toxicity (inhalation)
Not classied
Oral LD50
59 mg/kg body weight (reaction mass 3:1 of 5-
chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-
2H-isothiazol-3-one)
Other Toxicological Data
Property
Value
Dermal LD50 (rat)
> 1008 mg/kg body weight (Guideline: EPA OPP 81-2,
OECD Guideline 402 - Acute Dermal Toxicity)
Dermal LD50 (general)
> 75 mg/kg body weight
Skin corrosion/irritation
Not classied
pH
3.5–4 (20°C, Concentration: 10 g/L)
Serious eye damage/irritation
Not classied
Sensitization (respiratory/skin)
Not classied
Germ cell mutagenicity
Not classied
Carcinogenicity
Not classied
Reproductive toxicity
Not classied
Specic target organ toxicity (STOT), single exposure
Not classied
Specic target organ toxicity (STOT), repeated
exposure
Not classied
Aspiration hazard
Not classied
LOAEL (rat/rabbit, 90 days)
0.525 mg/kg body weight/day (Guideline: EPA OPP
82-3, Subchronic Dermal Toxicity, 90 Days)
11.2 Additional Information on Other Hazards
No additional information available.
SECTION 12: Ecological Information
12.1 Toxicity
Parameter
Classication/Value
General Ecology
No quantitative data available regarding the
ecological eects of this product.
Hazard for the aquatic environment, short-term
Not classied
Hazard for the aquatic environment, long-term
Not classied
Substance
Value
Reaction mass (3:1) of 5-chloro-2-methyl-2H-
isothiazol-3-one and 2-methyl-2H-isothiazol-3-one
(CAS: 55965-84-9)
CL50 - Fish: 0.19 mg/l (Oncorhynchus mykiss,
formerly known as Salmo gairdneri)
CL50 - Fish [2]: 0.28 mg/l (Lepomis macrochirus)
CE50 - Crustaceans [1]: 0.16 mg/l (Daphnia magna)
CE50 - Other aquatic organisms [2]: 0.126 mg/l
(Water eas)
NOEC (No Observed Eect Concentration) - Fish:
0.099 mg/l (Oncorhynchus mykiss) Duration: 28 days
12.2 Persistence and Degradability
No additional information available.
12.3 Bioaccumulation Potential
Substance
Value
Reaction mass (3:1) of 5-chloro-2-methyl-2H-
isothiazol-3-one and 2-methyl-2H-isothiazol-3-one
(CAS: 55965-84-9)
Partition coeicient n-octanol/water (Log Pow): 0.4
12.4 Mobility in Soil
No additional information available.
12.5 PBT and vPvB Assessment
This substance/mixture does not meet the PBT criteria of Annex XIII of REACH.
This substance/mixture does not meet the vPvB criteria of Annex XIII of REACH.
12.6 Endocrine Disrupting Properties
No additional information available.
12.7 Other Adverse Eects
No additional information available.
SECTION 13: Disposal Considerations
13.1 Waste Treatment Methods
Parameter
Details
Methods of waste treatment
Dispose of the contents/container in accordance
with the sorting instructions of an authorized waste
collection agent.
Recommendations for the disposal of the
product/packaging
Destroy safely in accordance with local and national
regulations.
Additional information
Waste codes should be assigned by the user,
preferably in coordination with the authorities
responsible for waste disposal.
European Waste Catalogue Code (EWC)
20 01 29*: Detergents containing hazardous substances
R/D Code
D10: Incineration on land
SECTION 14: Transport Information
Transport Regulation
ADR
IATA
14.1 UN Number or ID
Number
Not applicable
Not applicable
Not applicable
14.2 UN Proper
Shipping Name
Not applicable
Not applicable
Not applicable
14.3 Transport Hazard
Classes
Not applicable
Not applicable
Not applicable
14.4 Packing Group
Not applicable
Not applicable
Not applicable
14.5 Environmental
Hazards
Not applicable
Not applicable
Not applicable
14.6 Special Precautions for the User
Transport by land: Not applicable
14.7 Transport in Bulk According to IMO Instruments
Not applicable
SECTION 15: Regulatory Information
15.1 Specic Regulations/Legislation for the Substance or Mixture in Terms of Health, Safety, and the
Environment
15.1.1 EU Regulations
Other information, regulatory provisions: Regulation related to detergents.
Annex XVII of REACH (Restriction Conditions):
o Does not contain substances listed in Annex XVII of REACH (Restriction Conditions).
Annex XIV of REACH (Authorization List):
o Does not contain substances listed in Annex XIV of REACH (Authorization List).
List of Substances of Very High Concern (SVHC) of REACH:
o Does not contain substances included in the candidate list of SVHC of REACH.
PIC Regulation (EU No. 649/2012, Prior Informed Consent):
o Does not contain substances listed in the PIC list (related to the export and import of hazardous
chemicals).
POP Regulation (EU 2019/1021, Persistent Organic Pollutants):
o Does not contain substances listed in the Persistent Organic Pollutants (POP) list.
Regulation on Substances that Deplete the Ozone Layer (EU No. 1005/2009):
o Does not contain substances listed as ozone-depleting substances.
Regulation on Explosives Precursors (EU 2019/1148):
o Does not contain substances listed as explosives precursors.
Regulation on Drug Precursors (EC No. 273/2004):
o Does not contain substances listed as drug precursors.
15.1.2 National Regulations
No additional information available.
15.2 Chemical Safety Assessment
No chemical safety assessment has been carried out.
SECTION 16: Other Information
Abbreviations and Acronyms
Denition
ADN
European Agreement concerning the International
Carriage of Dangerous Goods by Inland Waterways
ADR
European Agreement concerning the International
Carriage of Dangerous Goods by Road
ATE
Acute Toxicity Estimate
Acronym
Denition
BCF
Bioconcentration Factor
VLB
Biological Limit Value
CBO
Biochemical Oxygen Demand (BOD)
CQO
Chemical Oxygen Demand (COD)
DMEL
Derived Minimal Eect Level
DNEL
Derived No-Eect Level
N.º CE
EC Number
CE50
Median Eective Concentration
EN
European Standard
CIIC
International Agency for Research on Cancer
IATA
International Air Transport Association
IMDG
International Maritime Dangerous Goods Code
CL50
Median Lethal Concentration
DL50
Median Lethal Dose
LOAEL
Lowest Observed Adverse Eect Level
NOAEC
No Observed Adverse Eect Concentration
NOAEL
No Observed Adverse Eect Level
NOEC
No Observed Eect Concentration
OECD
Organization for Economic Cooperation and
Development
PBT
Persistent, Bioaccumulative, and Toxic
PNEC
Predicted No-Eect Concentration
RID
Regulations concerning the International Transport
of Dangerous Goods by Rail
FDS
Safety Data Sheet
STP
Sewage Treatment Plant
CTeO
Theoretical Oxygen Demand (ThOD)
TLM
Median Tolerance Limit
COV
Volatile Organic Compounds
N.º CAS
CAS Number
N.O.S.
Not Otherwise Specied
mPmB
Very Persistent and Very Bioaccumulative
ED
Endocrine Disrupting Properties
Phrase
Description
Acute Tox. 2 (Dermal)
Acute toxicity (dermal), category 2
Acute Tox. 2 (Inhalation)
Acute toxicity (inhalation), category 2
Acute Tox. 3 (Oral)
Acute toxicity (oral), category 3
Aquatic Acute 1
Hazardous to the aquatic environment – acute
hazard, category 1
Aquatic Chronic 1
Hazardous to the aquatic environment – chronic
hazard, category 1
EUH208
Contains reaction mass (3:1) of 5-chloro-2-methyl-
2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-
one (CAS: 55965-84-9). May cause an allergic
reaction.
Eye Dam. 1
Causes serious eye damage, category 1
Eye Irrit. 2
Causes serious eye irritation, category 2
H301
Toxic if swallowed.
H310
Fatal in contact with skin.
H314
Causes severe skin burns and eye damage.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H318
Causes serious eye damage.
H319
Causes serious eye irritation.
H330
Fatal if inhaled.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long-lasting eects.
Skin Corr. 1C
Skin corrosion/irritation, category 1C
Skin Sens. 1A
Skin sensitization, category 1A
Classication complies with: ATP 12.
Note: This information is based on our current knowledge and is intended to describe the product for health,
safety, and environmental purposes only. It should not be interpreted as guaranteeing specic product
properties.